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国家自然科学基金(51011130028)

作品数:2 被引量:8H指数:2
相关作者:施敏敏更多>>
相关机构:浙江大学更多>>
发文基金:国家自然科学基金国家高技术研究发展计划更多>>
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新型窄带隙聚方酸菁的合成与光电性质被引量:2
2012年
为了寻找更好的聚合物太阳能电池材料,我们首先通过Leimgruber-Batho法合成了苯并双吡咯M1及其正丁基取代的衍生物M1a,并以它们为给电子性单体,分别与吸电子性单体方酸交替共聚得到聚合物P1和P1a。用TGA、GPC表征聚合物的热稳定性和分子量,并通过紫外-可见光吸收光谱、循环伏安法研究了它们的光电性能。结果表明,两种聚合物分解温度均高于300℃,其中P1a的紫外-可见光最大吸收峰出现在597nm,带隙为1.73eV,而且其LUMO能级为-3.85eV,与最常用的有机n型材料PCBM的HOMO能级相当(-3.91eV),有可能在聚合物太阳能电池中得到应用。
王承哲施敏敏陈红征
关键词:光电性质
Unique synthesis of graphene-based materials for clean energy and biological sensing applications被引量:6
2012年
Graphene has unique physical properties,and a variety of proof-of-concept devices based on graphene have been demonstated.A prerequisite for the application of graphene is its production in a controlled manner because the number of graphene layers and the defects in these layers significantly influence transport properties.In this paper,we briefly review our recent work on the controlled synthesis of graphene and graphene-based composites,the development of methods to characterize graphene layers,and the use of graphene in clean energy applications and for rapid DNA sequencing.For example,we have used Auger electron spectroscopy to characterize the number and structure of graphene layers,produced single-layer graphene over a whole Ni film substrate,synthesized well-dispersed reduced graphene oxide that was uniformly grafted with unique gold nanodots,and fabricated graphene nanoscrolls.We have also explored applications of graphene in organic solar cells and direct,ultrafast DNA sequencing.Finally,we address the challenges that graphene still face in its synthesis and clean energy and biological sensing applications.
XUMingSheng GAO Yan YANG Xi CHEN HongZheng
关键词:GRAPHENECHEMICALBIOLOGICALCHEMICALSEGREGATIONSEQUENCING
POLYMER-INORGANIC HYBRID SOLAR CELLS:MATERIALS SYNTHESIS AND INTERFACE ENGINEERING
<正>Organic solar cells,especially polymer solar cells have attracted enormous interests both in scientific com...
Weifei Fu
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