Two novel compounds, {[Co2（epda）2（4,4＇-bpy）（H20）z]＇3H20}n 1 and {[Co2（epda）2（bpe）（HzO）z]＇3HzO}n 2 （H2epda = 5-ethyl-pyridine-2,3-dicarboxylic acid, 4,4＇-bpy = 4,4＇-bipyridine and bpe = 1,2-di（4-pyridyl）ethylene） were solvothermally synthesized and charac- terized by elemental analysis, IR spectroscopy, thermogravimetric analysis （TGA）, and single- crystal X-ray diffraction. Complex 1 is ofmonoclinic system, space group P21/c with a = 13.344（5）, b = 14.724（5）, c = 8.267（3） A, fl = 105.840（4）~, V= 1562.5（10） A3, Dc = 1.480 g/cm3, Mr = 375.19, Z = 4, F（000） = 712, gl = 1.121 mm-1, the final R = 0.0512 and wR = 0.1260 for 2890 observed reflections with I 〉 2σ（I）. 2 belongs to the monoclinic system, space group P21/c with a = 14.224（4）, b = 14.726（4）, c = 8.287（2） A,β = 99.696（4）°, V= 1711.1（9） A3, Dc = 1.402 g/cm3, Mr = 388.21, Z = 4, F（000） = 740, kt = 1.027 mm-1, the final R = 0.0354 and wR = 0.0862 for 12237 observed reflections with I 〉 2a（/）. Both complexes present intimately related structures featuring infinite Co-carboxylate layers of [Con（epda）（H20）]n pillared by 4,4＇-bpy （or bpe） molecule to produce the microporous frameworks, Unambiguously indicating that pore dimensions of the framework are regulated by the N,N＇-donor pillars.
Six new ZnIIcoordination polymers,namely,[Zn(CH3-ip)(btb)]n·2H2O(1),[Zn2(CH3-ip)2(btb)1.5]n(2),[Zn(CH3-ip)(btp...
Min-Le Han,Lu-Fang Ma *,Xin-Hong Chang,Li-Ya Wang,* Zhen-Zhen Shi College of Chemistry and Chemical Engineering,Luoyang Normal University,Luoyang,471022
A new complex [Co（NIT-1′-MeBzIm）2Cl2]（NIT-1′-MeBzIm = 2-{2′-[（l′-methyl）-benzimidazolyl]}-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide） has been prepared and structurally characterized by X-ray diffraction method.The complex crystallizes in the monoclinic system,space group C2/c,Z = 4.Crystal data：C30H38Cl2CoN8O4,Mr = 704.51,a = 17.074（3）,b = 21.350（3）,c = 11.6962（19）,β = 108.879（2）°,V = 4034.3（11）3,Dc = 1.160 g/cm3,μ（MoKα） = 0.597 mm-1,F（000） = 1468,R = 0.0422 and wR = 0.1141 for 2577 observed reflections with I 2σ（I）.X-ray analysis reveals that the Co（Ⅱ） ion is six-coordinated with a distorted octahedral geometry.Temperature dependence of susceptibility measurements shows the existence of antiferromagnetic interactions between the Co（Ⅱ） ion and the radicals（J =-52.88 cm-1）.
A new one-dimensional aluminum fluorophosphate, AlP2O5（OH）3F·0.5[H2dien] （dien=diethylenetriamine）, was solvothermally synthesized by using organic amine as the structure directing agent, and its structure was determined by single-crystal X-ray diffraction. The complex inorganic architecture consists of trans-corner-sharing AlO4F2 octahedra chain decorated by phosphate tetrahedra along both sides of the -F-Al-F-Al-F- backbone displaying a series of Al2P three-membered rings, which will represent a new fundamental structural type in metal phosphates. The results of CHN elemental analysis, EDS, and TGA are also presented. Crystal data： C4H18Al2F2N3O16P4, monoclinic, space group P21/c with a=6.9107（14）, b=15.749（3）, c=8.9741（18） , β=109.829（2）o, V=918.8（3） 3, Z=2, Mr=580.05, Dc=2.097 g/cm3, μ=0.618 mm-1, S=1.022, F（000）=590, the final R=0.0510 and wR=0.1284 for 1607 observed reflections （I 〉 2σ（I））.
A new cadmium（II） polymer based on imidazole derivative, formulated as [Cd（Hiba）2]n 1, H2iba = 4-（1-H-imidazol-2-yl） benzoic acid）, has been synthesized under hydro- thermal conditions. The compound crystallizes in triclinic system, space group P1 with a = 7.062（4）, b = 10.840（7）, c = 13.099（8） A, a = 98.102（7）, fl = 101.524（7）, y = I07.961（7）°, V= 912.3（10） A3, Z = 2, Mr = 486.75, Dc = 1.772 Mg/m3,/t = 1.234 mm-1, F（000） = 484, the final R = 0.0735 and wR = 0.1739 for 2154 observed reflections with 1 〉 20（I）. Polymer 1 consists of （Cd-Hiba）2 zigzag chains, which are further linked by hydrogen bonding to extend into a two-dimensional （2D） corrugated-shape sheet structure. The 2D structures are further connected into a 3D supramolecular edifice through hydrogen bonding. The polymer exhibits exceptional high thermal stability. The bulk purity of the materials of 1 was confirmed through the powder X-ray diffraction （PXRD） patterns. The luminescent property of polymer I has also been investigated.
A novel azide-bridged copper（Ⅱ） coordination polymer, [Cu3（NITpPy）4（N3）6]n （NITpPy = 4-pyridyl-4,4,5,5-tetramethylimidazline-3-oxide-1-oxyl）, was structurally and magnetically characterized. It crystallizes in the triclinic space group P with a = 7.6932（10）, b = 14.5556（19）, c = 16.122（2） , α = 108.443（2）, β = 95.251（2）, γ = 104.236（2）°, V = 1631.7（4） 3, C48H64Cu3N30O8, Mr = 1379.87, Z = 1, Dc = 1.404 g/cm3, μ（MoKα） = 1.041 mm-1, F（000） = 713, the R = 0.0510 and wR = 0.1185 for 4285 observed reflections with I 2σ（I）. X-ray analysis reveals that the Cu（Ⅱ） ions are linked by nitrogen atom of μ1,1 azido ligands to form a Cu-Cu-Cu unit. The units are linked by μ1,3 azido ligands through a bridging style to form a one-dimensional coordination polymer. The variable-temperature magnetic susceptibility data of the complex show ferromagnetic interactions in the complex.
