According to the existing concrete core samples obtained in site, chloride concentration and porosity of existing normal hydraulic concrete were measured, and chloride diffusivity in existing hydraulic concrete was studied. By Fick's second law, the chloride diffusion coefficients in the steady diffusion area were calculated. The chloride diffusion of different mix proportion concrete was tested, and chloride diffusion coefficients and porosities of freshly concrete were measured, moreover, the relationship between diffusion coefficient and porosity was analyzed. The results show that the varying law of chloride diffusion coefficient with exposure time of existing concrete can be predicted in a better way by Fick's second law and water-cement ratios or porosity of concrete and chloride concentration in existing concrete.
