采用粉末冶金修复工艺(China Powder Metallurgy,CPM),利用2种分别混有微量硼合金和纳米镍粉的镍基高温合金粉末对K403缺损叶片进行修复再制造。采用X射线衍射、扫描电子显微镜(SEM)、EDX能谱和电子探针(EPMA)对叶片修复区的相组成、宏观形貌及微观组织进行分析;同时对修复区致密化和界面连接机理进行初步探讨。结果表明,选用合适的修复粉末,用CPM方法能够将缺损的叶片再制造成原有形状与尺寸;混合硼合金的修复粉末对K403合金的修复效果较好;硼元素的扩散对修复区致密化和界面连接起重要作用,期间发生的反应为Ni m B n+(Cr,W)→γ+(Cr2,W)B2;经计算,在CPM工艺条件下,界面区的硼浓度可以降低至共晶浓度以下。
An 8 mm-high NiCoCrAlYTa coating was epitaxially built-up on a directionally solidified (DS) Ni-based superalloy blade tip by electro-spark deposition.Epitaxial morphologies of the coating and its microstructural characteristics were investigated by means of SEM,XRD and TEM etc.It is observed that the fine column-like dendrites originated from the γ'-particles or γ'-clusters of the DS substrate and are un-continuously coarsened.The β-phase particles precipitate and grow eutectically with the γ-phase.The orientation of fine column dendrites depends on electro-spark deposition processing parameters and the microstructure can be characterized with superfine γ and β phases.
