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国家自然科学基金(40373013)

作品数:4 被引量:190H指数:4
相关作者:高山胡兆初柳小明第五春荣刘晔更多>>
相关机构:中国地质大学西北大学更多>>
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Geochemistry and U-Pb zircon geochronology of Late-Mesozoic lavas from Xishan,Beijing被引量:22
2006年
Zircon U-Pb dating by both SHRIMP and LA-ICP-MS and geochemical study of theTiaojishan Formation and the Donglintai Formation from Xishan, Beijing, reveal that ages of upperlavas of Tiaojishan Formation and Middle of Donglintai Formation are 137.1 ± 4.5 Ma(2σ) and 130—134 Ma, respectively. The fomer is slightly older than the latter and the age difference betweenthese two formations is less than 5 Ma. These lines of evidence prove that the two volcanoes eruptedwithin a short time. The age of the Tiaojishan Formation from Xishan, Beijing is distinctivelydifferent from that of the Chende Basin. This indicated that the ages of Tiaojishan lavas varied indifferent regions. The Tiaojishan Formation consists of typical adakite (SiO_2 = 56%, Na_2O =3.99—6.17, Na_2O/K_2O = 2.2 -3.1, Sr = 680-1074 x 10^(-6), Y = 13.2-16.3 x 10^(-6), Yb = 1.13-1.52x 10^(-6), Sr/Y = 43-66), high-Mg adakite and high-Mg andesite (Mg# = 54—55). Features ofcontinental crust of adakite from the Tiaojishan Formation and its syngeneric middle silicic vocanicrocks, such as typical Nd-Ta negative abnormality and Pb possive abnormality, indicate that theselavas are originated from partial melts of continental crust. These results suggest that the adakitefrom the Tiaojishan Formation of Xishan, Beijing derived from thickened eclogitic lower crust andlithosphere beneath the North China craton at mesozoic that was foundered into the aesthenosphere,and subsequenctly partially melted and interacted with mantle olivine during melts upward migration.The age of lavas from the Tiaojishan Formation restrained the foundation which should last at leastuntil 137 Ma. Lavas of the Donglintai Formation are rhyolith and andesite with normal Mg# and thusthey did not interact with the mantle. These lavas represent remobilized melts of lower crustmaterial caused by mantle aesthenosphere upwelling migration induced by foundation.
YUAN Honglin1, LIU Xiaoming1, LIU Yongsheng2, GAO Shan1,2 & LING Wenli2 1. Key Laboratory of Continental Dynamics, Northwest University, Xi’an 710069, China
Geochemistry of high-Mg andesites from the early Cretaceous Yixian Formation, western Liaoning: Implications for lower crustal delamination and Sr/Y variations被引量:20
2006年
85 volcanic rocks of the Yixian Formation from the Sihetun type section werecollected and analyzed for geochemical and isotopic compositions. Major element compositionsindicate that the Sihetun volcanic rocks are high magnesium andesites with some basalts occurring atthe bottom of section. The Sihetun high magnesium andesites (SiO_2 = 52.82-59.31 wt%, Al_2O_3=14.15-16.35wt%) show many characteristics of adakites such as depletion in heavy rare-earth elements(HREE; Yb = 1.03-1.88 μg/g) and Y(12-20 μg/g) and high Sr (620-1323 μg/g) and Sr/Y(32-88), withhigh La_N/Yb_N ratio (10-25). They share similar major and trace element characteristics to volcanicrocks from the Xinglonggou Formation except their lower Nd isotope ratios (^(143)Nd/^(144)Nd(130Ma) = 0.5118-0.5119, ε_(Nd) (130Ma) = -11.6-13.8, ^(87)Sr/^(86)Sr (130 Ma) = 0.7058-0.7064.They were interpreted in a way that eclogite that formed at the base of thickened Archean lowercrust of the North China craton foundered into the convecting mantle and subsequently melted andinteracted with peridotite. However, compared to the Xinglonggou volcanic rocks, the source of theSihetun magma contained more ancient continental crustal material in order to explain its evolved Ndisotopes. The age of the Sihetun Formation was 120 to 130 Ma, and this indicates that delaminationlasted to the early Cretaceous period. The Sr contents and Sr/Y ratios of the Sihetun high-Mgandesites show significant negative correlations with SiO_2 for samples with SiO_2 > 56%. Thesesuggest that the Sr and Sr/Y values were reduced due to fractional crystallization of plagioclase.Accordingly, the effect of crystallization on volcanic Sr and Sr/Y ratio has to be taken intoaccount.
WANG Xiaorui1, GAO Shan1,2, LIU Xiaoming1, YUAN Honglin1, HU Zhaochu1, ZHANG Hong1,3 & WANG Xuance4 1. State Key Laboratory of Continental Dynamics, Department of Geology, Northwest University, Xi`an 710069, China
关键词:YIXIAN
ICP-MS测定地质样品中37个元素的准确度和长期稳定性分析被引量:139
2007年
对Elan6100DRC型ICP-MS近五年来所测得的国际地质标样BHVO-1(玄武岩)和AGV-1(安山岩)中的37个元素的测定值以及仪器灵敏度的长期漂移情况进行了统计分析(共计146次)。结果表明,几年来ICP-MS所测数据的长期稳定性和准确度都较好,除个别元素Li(BHVO-1)、Be(BHVO-1))、Cr(AGV-1)、Cs(BHVO-1)和Pb(BHVO-1)的相对误差(与参考值比较)接近或略大于10%外,绝大多数元素的相对误差和相对标准偏差(RSD,测定值之间,n=146)都在5%以内;仪器灵敏度并不是随着时间一直往下漂,有的是往上漂的,也有上下漂的,即使是在同一时间内,有的元素灵敏度往上漂,而有的往下漂。常用的内标法无法较好校正这种漂移,而需要采用内外标相结合的校正方法。不同批次,210个各种地质样品中Rb、Sr、Zr和Nb的XRF和ICP-MS分析结果对比情况表明,绝大多数样品中Rb、Sr、Zr和Nb的ICP-MS和XRF的测定值的相对误差小于10%。以上的分析结果表明,我们实验室所建立的以密闭高温高压消解技术为样品前处理方法,以模拟地壳样品中元素天然丰度比的基体匹配校正标准溶液为外标和以Rh为内标结合外标校正的ICP-MS多元素分析方法具有非常好的准确度和长期稳定性。
刘晔柳小明胡兆初第五春荣袁洪林高山
关键词:ICP-MS地质样品
华北克拉通南缘太古—元古宙界线安沟群火山岩的年龄及地球化学被引量:12
2005年
河南登封地区登封群和安沟群记录了华北克拉通南缘太古宙—元古宙界线两侧地层较完整的演化历史.Krneretal.(1988)曾获得登封群顶部老羊沟组变英安岩中锆石的SHRIMP年龄为(2512±12)Ma.本研究获得不整合覆盖在登封群之上的安沟群同源双峰式拉斑玄武岩和英安岩7个样品全岩SmNd同位素等时线年龄为(2507±96)Ma,MSWD=6.3,初始143Nd/144Nd=0.509560±0.000093,εNd(2.5Ga)=3.27±1.82.上述年龄制约了登封群顶部长英质火山岩与安沟群底部的双峰火山岩之间的年龄相差最多应不超过113Ma.安沟群演化程度较低的拉斑玄武岩La/Nb比值为0.66~1.14,与软流圈地幔的比值接近,而明显不同于岛弧玄武岩(La/Nb<2.0).结合安沟群火山岩的双峰特征,这些说明太古宙末或元古宙初期至少华北克拉通南缘已进入陆内裂谷伸展环境.
高山周炼凌文黎刘勇胜周鼎武
关键词:太古宙SM-ND同位素
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