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国家自然科学基金(40405023)

作品数:4 被引量:35H指数:3
相关作者:李旭祥曹军骥沈振兴刘随心周娟更多>>
相关机构:中国科学院西安交通大学中国石油天然气集团公司更多>>
发文基金:国家自然科学基金陕西省自然科学基金国家重点基础研究发展计划更多>>
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Chemical characteristics of aerosol particles (PM_(2.5)) at a site of Horqin Sand-land in northeast China被引量:4
2006年
The objective of this study was to characterize the mass concentration and chemical composition of aerosol particles(PM2.5) collected at Tongliao(Inner Mongolia Autonomous Region, China), a site in Horqin Sand-land in northeast China. During spring 2005, the mass concentration for PM2.5 was (126±71)μg/m^3 in average. Five dust storm events were monitored with higher concentration of (255 ± 77)μg/m^3 in average than the non dusty days of (106 ± 44)μg/m^3. Concentrations for 20 elements were obtained by the PIXE method. Mass concentrations of ALl, Mg, Si, K, Ca, Ti, Mn, and V, which increased with the PM2.5 concentration, were higher than the pollution elements (S, Cl, Zn, Ar, Se, Br, and Pb). Enrichment factor relative to crust material was also calculated, which showed dust trace elements were mainly from earth upper crust and pollution elements were dominated the anthropogenic aerosols. The Si/Al, Ca/Al, and Fe/Al ratios in PM2.5 samples at Tongliao were 4.07, 0.94, and 0.82, respectively, which were remarkably different with those on other source regions, such as "Western desert source region", "North desert source region" and central Asia source. Air mass back-trajectory analysis identified three kinds of general pathways were associated with the aerosol particle transport to Tongliao, but have the similar elemental ratios, implying that elemental signatures for dust aerosol from Horqin Sand-land were different with other regions.
SHEN Zhen-xingCAO Jun-jiLI Xu-xiangWANG Ya-qiangJIE Dong-meiZHANG Xiao-ye
前处理方法对微量沙尘气溶胶样品矿物实验结果的影响被引量:1
2006年
为了探讨前处理方法对微量沙尘气溶胶样品矿物分析结果的影响,对2002年春季甘肃敦煌采集的3次沙尘暴样品分别进行了5次重复前处理和矿物分析实验研究.X射线衍射分析显示,8种沙尘气溶胶组成矿物的5次实验结果的标准偏差相对于平均值均较小.同时计算的石英、斜长石、方解石、伊利石、绿泥石和高岭石等沙尘气溶胶的主要组成矿物的相对标准偏差均小于10%,表明前处理方法对微量沙尘气溶胶样品的矿物分析结果影响较小.
沈振兴李丽珍游建昌曹军骥李旭祥
关键词:前处理沙尘气溶胶矿物分析
Mass Concentration and Mineralogical Characteristics of Aerosol Particles Collected at Dunhuang During ACE-Asia被引量:10
2006年
Measurements were performed in spring 2001 and 2002 to determine the characteristics of soil dust in the Chinese desert region of Dunhuang, one of the ground sites of the Asia-Pacific Regional Aerosol Characterization Experiment (ACE-Asia). The mean mass concentrations of total suspended particle matter during the spring of 2001 and 2002 were 317μg m^-3 and 307μg m^-3, respectively. Eleven dust storm events were observed with a mean aerosol concentration of 1095μg m^-3, while the non-dusty days with calm or weak wind speed had a background aerosol loading of 196μg m^-3 on average in the springtime. The main minerals detected in the aerosol samples by X-ray diffraction were illite, kaolinite, chlorite, quartz, feldspar, calcite and dolomite. Gypsum, halite and amphibole were also detected in a few samples. The mineralogical data also show that Asian dust is characterized by a kaolinite to chlorite (K/C) ratio lower than 1 whereas Saharan dust exhibits a K/C ratio larger than 2. Air mass back-trajectory analysis show that three families of pathways are associated with the aerosol particle transport to Dunhuang, but these have similar K/C ratios, which further demonstrates that the mineralogical characteristics of Asian dust are different from African dust.
沈振兴曹军骥李旭祥Tomoaki OKUDA王亚强张小曳
西安冬季大气亚微米颗粒物的化学特征及来源解析被引量:21
2008年
为了探讨西安市冬季大气亚微米颗粒物的污染水平及化学组成,2006年12月每天收集西安大气亚微米颗粒物(PM1.0)样品,并对PM1.0的质量浓度及其其中的11种水溶性离子、元素碳(EC)和有机碳(OC)及8个碳组分进行了分析.结果显示:西安市冬季大气PM1.0的平均质量浓度为149.7μg.m-3;分析的11种阴、阳离子(Na+、NH4+、K+、Mg2+、Ca2+、F-、Cl-、Br-、NO2-、NO3-和SO42-)的质量浓度占到PM1.0的46%,表明水溶性组分是大气亚微米颗粒物的主要组成之一;OC的质量浓度(ρ(OC)=(23.7±10.27)μg.m-3)明显高于EC的((ρ(EC)=(4.6±1.8)μg.m-3),碳气溶胶的平均质量浓度为42.5μg.m-3,占到PM1.0质量浓度的28.4%;对8个碳组分的因子分析结果显示,燃煤及汽油车排放、柴油车排放和生物质燃烧对碳颗粒的贡献分别为45.3%、24.2%和23.5%.
沈振兴韩月梅周娟曹军骥李旭祥刘随心
关键词:水溶性离子碳气溶胶
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