A facile "click chemistry" approach to functionalize 2D macromolecules of graphene oxide nanosheets with poly(ethylene glycol) of different molecular weights,polystyrene,palmitic acid and various amino acids was presented.FTIR,TGA,Raman spectroscopy,XPS,XRD,TEM,AFM and SEM were utilized to characterize the products.High degree of functionalization was achieved on the flat surfaces of graphene oxide,affording polymer-grafted 2D brushes and amino acids-immobilized nanosheets,which show improved solubility in organic solvents.The click chemistry strategy reported herein provides a facile and general method for functionalization of graphene oxide with macromolecules and desired biomolecules.
Following the conventional carbon allotropes of diamond and graphite,fullerene,carbon nanotubes(CNTs) and graphene as 0D,1D and 2D graphitic macromolecules have been discovered recently in succession,declaring the unlimited potential of carbon-based nanomaterials and nanotechnology.Although CNTs exhibit significant potential applications in advanced materials and other fields due to their extraordinary mechanical strength and electrical/thermal conductivity properties,their low solubility,poor wettability and bad dispersibility in common solvents and solid matrices have limited their processing and applications.Thus,the attempt to achieve wettable/processable CNTs by functionalization has attracted increasing attention in both scientific and industrial communities.In recent years,azide chemistry has been demonstrated as a powerful means to covalently modify CNTs.It consists of two major approaches:click chemistry and nitrene chemistry,which both involve the usage of various azide compounds.The former one is based on highly reactive and stereospecifical Cu(I) catalyzed azide-alkyne cycloaddition reaction;the latter one is based on the electrophilic attack to unsaturated bonds of CNTs with nitrenes as reactive intermediates formed from thermolysis or photolysis of azides.In this mini-review paper,the azide chemistry to functionalize CNTs is highlighted and the corresponding functionalization routes to build CNT-based complex structures are also discussed.Besides,covalent functionalizations of other graphitic nanomaterials such as fullerence and graphene,via azide chemistry,are commented briefly.
Graphene,a perfect two-dimensional (2D) nanostructure,is an ideal template for 2D material design.We developed a graphenetemplated method to synthesize 2D silica nanosheets through the crosslinking of poly(3-methacryloxypropyl trimethoxysilane)grafted graphene oxide (GO-g-PMPS),followed by pyrolysis at 700℃ for 10 h.
Reversible assembly and disassembly of rod-like large complex micelles have been achieved by applying photoswitching of supramolecular inclusion and exclusion of azobenzene-functionalized hyperbranched polyglycerol and α-cyclodextrin as driving force, promising a versatile system for self-assembly switched by light. Hydrogen-nuclear magnetic resonance (1H NMR) and Fourier transform infrared (FT-IR) spectroscopy were applied to characterize the azobenzene-functionalized hyperbranched polyglycerol. Atomic force microscopy (AFM), transmission electron microscopy (TEM) and dynamic laser light scattering (DLS) were employed to investigate and track the morphology of the rod-like large complex micelles before and after irradiation of UV light.
