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国家自然科学基金(20571032)

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Hydrothermal synthesis and structural characterization of a series of new molybdenum/tungsten arsenate clusters
<正>The study of organic-inorganic hybrid polyoxometalates(POMs)is a very active and expanding area because of ...
Hai-Hui Yu Xiao-Bing Cui Ji-Wen Cui Ji-Qing Xu Tie-Gang Wang. College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,Jilin University,Changchun,Jilin,130023,P.R..China.
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几个卤或拟卤化物与有机配体1:1的加合物的结构性质
In this abstract, we reported the structure characterization of 1:1 adducts of metal halides and organic ligan...
于杰辉侯芹张潇徐吉庆
关键词:金属卤化物有机配体加合物晶体结构
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Novel Metal-organic Framework Compound Pb(C_5H_4NCOO)_2 Showing One-dimensional Channel Defined as Four Leads and Four Nicotinic Acids被引量:1
2009年
A novel metal-organic framework(MOF) compound of Pb(C5H4NCOO)2 was hydrothermally synthesized and structurally determined by X-ray single-crystal diffraction. The data of unit cell:orthorhombic space group Pccn,a=1.0325(2) nm,b=1.3597(3) nm,c=0.8499(2) nm,V=1.1931(4) nm3,Z=4,Dc=2.513 g/cm3,R1=0.047 were obtained on the basis of 1365 reflections with Fo>2σ(Fo). PbN2O6 polyhedron adopts the distorted cubic configuration which is assigned to the holodirected geometry. These PbN2O6 polyhedra can form the zigzag chain by edge-sharing mode along(001) direction. Pb atom is connected by six nicotinic acid molecules,leading neutral 3D metal-organic framework with a channel defined by four Pb atoms and four nicotinic acid molecules.
XU Xiao-yu ZHOU Rui-sha SONG Jiang-feng XU Ji-qing
关键词:金属有机铅原子X射线单晶衍射
Synthesis and crystal structure of a novel 3D Cu-ipO polymer with mixed penta-and hepta-coordinate copper centers
<正>The considerable emphasis has been placed on the investigation of copper(Ⅱ)complexes because of their inter...
Xiao-Yu Xu Jiang-Feng Song Rui-Sha Zhou Ji-Qing Xu~(*7) Tie-Gang Wang College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,Jilin University,Changchun,Jilin,130023,P.R.China.
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杂多酸[(H3dien)2(P2Mo5O23)](dien=diethylenetriamine)的水热合成及晶体结构
The crystal of [(H3dien)2(P2Mo5O23)] (dien = diethylenetriamine) consist of the heteropolyanion, (P2Mo5O23)6- ...
张潇卢静于杰辉徐吉庆
关键词:水热合成杂多酸晶体结构
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Synthesis,crystal structures,luminescence and magnetism for a series of lanthanide-carboxylate polymers
<正>Lanthanide complexes have received significant attention in the current research not only because of their ...
Rui-Sha Zhou Xiao-Yu Xu Jiang-Feng Song Tie Gang Wang Ji-Qing Xu College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,Jilin University,Changchun,Jilin,130023,P.R..China.
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一种新颖的铜(Ⅱ)配合物的合成和结构:(C2H4OH)2N(C2H4O)Cu(SCN)
A new compound (C2H4OH)2N(C2H4O)Cu(SCN) was synthesized from the acetonitrile solution of NaSCN, CuCl2 and N(C...
张潇于杰辉卢静徐吉庆
关键词:配合物氢键单晶结构
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Hydrothermal Synthesis and Structural characterization of two Bicapped Tri-supported Keggin Mixed Molybdenum-Vanadium Polyoxometalates
<正>Recently,the study of polyoxometalates covalently linked by transition metal complex fragments has been an ...
Ji-Wen Cui~(a,b) Xiao-Bing,Cui~a Hai-Hui Yu~a Wei-Jie Duan~a Ji-Qing Xu~(a*) Tie-Gang Wang~a a College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,Jilin University,Changchun 130021,China. b College of Chemistry and Pharmacy,Jiamusi University,Jiamusi 154000,China
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