<正>The study of organic-inorganic hybrid polyoxometalates(POMs)is a very active and expanding area because of ...
Hai-Hui Yu Xiao-Bing Cui Ji-Wen Cui Ji-Qing Xu Tie-Gang Wang. College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,Jilin University,Changchun,Jilin,130023,P.R..China.
A novel metal-organic framework(MOF) compound of Pb(C5H4NCOO)2 was hydrothermally synthesized and structurally determined by X-ray single-crystal diffraction. The data of unit cell:orthorhombic space group Pccn,a=1.0325(2) nm,b=1.3597(3) nm,c=0.8499(2) nm,V=1.1931(4) nm3,Z=4,Dc=2.513 g/cm3,R1=0.047 were obtained on the basis of 1365 reflections with Fo>2σ(Fo). PbN2O6 polyhedron adopts the distorted cubic configuration which is assigned to the holodirected geometry. These PbN2O6 polyhedra can form the zigzag chain by edge-sharing mode along(001) direction. Pb atom is connected by six nicotinic acid molecules,leading neutral 3D metal-organic framework with a channel defined by four Pb atoms and four nicotinic acid molecules.
XU Xiao-yu ZHOU Rui-sha SONG Jiang-feng XU Ji-qing
<正>The considerable emphasis has been placed on the investigation of copper(Ⅱ)complexes because of their inter...
Xiao-Yu Xu Jiang-Feng Song Rui-Sha Zhou Ji-Qing Xu~(*7) Tie-Gang Wang College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,Jilin University,Changchun,Jilin,130023,P.R.China.
<正>Lanthanide complexes have received significant attention in the current research not only because of their ...
Rui-Sha Zhou Xiao-Yu Xu Jiang-Feng Song Tie Gang Wang Ji-Qing Xu College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,Jilin University,Changchun,Jilin,130023,P.R..China.
<正>Recently,the study of polyoxometalates covalently linked by transition metal complex fragments has been an ...
Ji-Wen Cui~(a,b) Xiao-Bing,Cui~a Hai-Hui Yu~a Wei-Jie Duan~a Ji-Qing Xu~(a*) Tie-Gang Wang~a a College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,Jilin University,Changchun 130021,China. b College of Chemistry and Pharmacy,Jiamusi University,Jiamusi 154000,China