SnO2-ln2O3 hierarchical microspheres were prepared by the hydrothermal and solvothermal method. The morphology, phase crystallinity of the obtained SnO2-In203 were measured by X-ray diffraetion(XRD), scan electron microscopy(SEM), respectively. A room temperature ozone sensor based on SnO2-In2O3 hierarchical microspheres was fabricated and investigated. The gas sensing properties of the sensor using SnO2-In2O3 strongly depended on the proportion of SnO2 and In2O3. The sensitivity and response/recovery speed were greatly enhanced by UV illumination. A gas sensing mechanism related to oxygen defect was suggested.
SUN Jian-boXU JingWANG BiaoSUN PengLIU Feng-minLU Ge-yu
Cuprous oxide(Cu2O),as an important p-type semiconductor,has been widely investigated due to its high electron transmission and facile preparation.However,the electrode made of only Cu2O has been rarely investigated.In order to demonstrate the possibility that material Cu2O can be applied to the electrode of p-type dye sensitized solar cells(DSSCs),the photo-electrodes made of prepared Cu2O powder and commercial Cu2O particles have been fabricated.The results show that the electrode based on as-prepared Cu2O(Cu2O-2) powder exhibits higher performance than that based on commercial Cu2O(Cu2O-1) particle.The device based on Cu2O-2 electrode reaches into an open-circuit voltage of 0.71 V,a short-circuit current density of 1.3 mA/cm^2,a fill factor(FF) of 46%,and a conversion efficiency of 0.42% measured under AM 1.5G(100 mW/cm^2) illumination.The enhancement performance of Cu2O-2 is attributed to the high dye adsorption of Cu2O-2 compared with that of Cu2O-1.To the best of our knowledge,this is the highest conversion efficiency value reported for solar cells based on Cu2O-DSSC.This work provides that Cu2O is also a candidate for constructing the electrode of p-type dye sensitized solar cells.
DU Sisi CHENG Pengfei SUN Peng WANG Biao CAI Yaxin LIU Fengmin ZHENG Jie LU Geyu