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国家自然科学基金(10974015)

作品数:4 被引量:1H指数:1
发文基金:国家自然科学基金国家重点基础研究发展计划更多>>
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端基取代基对镍连二硫烯与乙烯络合反应的影响
采用密度泛函理论在B3LYP/6-31G(d)水平上研究了端基取代基对镍连二硫烯与乙烯反应的影响。计算了具有不同端基取代基的镍连二硫烯与乙烯反应的势能面上各个驻点的几何构型、电子结构和热力学性质,利用内禀反应坐标计算法对...
韩清珍张和珍赵月红江兆潭温浩
关键词:乙烯密度泛函理论
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A theoretical and experimental evaluation of Ⅲ–nitride solar-blind UV photocathode被引量:1
2017年
We have developed a superior solar-blind ultraviolet (UV) photocathode with an AlxGa1_xrN photocathode (x ~ 0.45) in semi-transparent mode, and assessed spectra radiant sensitivity related to practical use. Betbre being grown over a basal plane sapphire substrate by low-pressure metal organic chemical vapor deposition (MOCVD), a reasonable design was made to the photocathode epitaxy structure, focusing on the AlxGa1_xN: Mg active layer, then followed by a comprehen- sive analysis of the structural and optical characterization. The spectra radiant sensitivity is peaked of 41.395 mA/W at wavelength 257 nm and then decreases by about 3 to 4 decades at 400 nm demonstrating the ability of this photocathode for solar-blind application prospects.
任彬郭晖石峰程宏昌刘晖刘健申志辉史衍丽刘培
关键词:PHOTOCATHODE
Quantum transport through a multi-quantum-dot-pair chain side-coupled with Majorana bound states
2016年
We investigate the quantum transport properties through a special kind of quantum dot(QD) system composed of a serially coupled multi-QD-pair(multi-QDP) chain and side-coupled Majorana bound states(MBSs) by using the Green functions method,where the conductance can be classified into two kinds:the electron tunneling(ET) conductance and the Andreev reflection(AR) one.First we find that for the nonzero MBS-QDP coupling a sharp AR-induced zero-bias conductance peak with the height of e^2/h is present(or absent) when the MBS is coupled to the far left(or the other) QDP.Moreover,the MBS-QDP coupling can suppress the ET conductance and strengthen the AR one,and further split into two sub-peaks each of the total conductance peaks of the isolated multi-QDPs,indicating that the MBS will make obvious influences on the competition between the ET and AR processes.Then we find that the tunneling rate ΓLis able to affect the conductances of leads L and R in different ways,demonstrating that there exists a ΓL-related competition between the AR and ET processes.Finally we consider the effect of the inter-MBS coupling on the conductances of the multi-QDP chains and it is shown that the inter-MBS coupling will split the zero-bias conductance peak with the height of e^2/h into two sub-peaks.As the inter-MBS coupling becomes stronger,the two sub-peaks are pushed away from each other and simultaneously become lower,which is opposite to that of the single QDP chain where the two sub-peaks with the height of about e^2/2h become higher.Also,the decay of the conductance sub-peaks with the increase of the MBS-QDP coupling becomes slower as the number of the QDPs becomes larger.This research should be an important extension in studying the transport properties in the kind of QD systems coupled with the side MBSs,which is helpful for understanding the nature of the MBSs,as well as the MBS-related QD transport properties.
江兆潭仲成成
Kondo transport through a quantum dot coupled with side quantum-dot structures
2010年
This paper investigates Kondo transport properties in a quadruple quantum dot (QD) based on the slave-boson mean field theory and the non-equilibrium Green's function. In the quadruple QD structure one Kondo-type QD sandwiched between two leads is side coupled to two separate QD structures: a single-QD atom and a double-QD molecule. It shows that the conductance valleys and peaks always appear in pairs and by tuning the energy levels in three side QDs, the one-, two-, or three-valley conductance pattern can be obtained. Furthermore, it finds that whether the valley and the peak can appear is closely dependent on the specific values of the interdot couplings and the energy level difference between the two QDs in the molecule. More interestingly, an extra novel conductance peak can be produced by the coexistence of the two different kinds of side QD structures.
江兆潭
端基取代基对镍连二硫烯与乙烯络合反应的影响
采用密度泛函理论在B3LYP/6-31G(d)水平上研究了端基取代基对镍连二硫烯与乙烯反应的影响。计算了具有不同端基取代基的镍连二硫烯与乙烯反应的势能面上各个驻点的几何构型、电子结构和热力学性质,利用内禀反应坐标计算法对...
韩清珍张和珍赵月红江兆潭温浩
关键词:乙烯密度泛函理论
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The calculation of energy gaps in small single-walled carbon nanotubes within a symmetry-adapted tight-binding model
2010年
This paper studies in detail the electronic properties of the semimetallic single-walled carbon nanotubes by applying the symmetry-adapted tight-binding model. It is found that the hybridization of π-σ states caused by the curvature produces an energy gap at the vicinity of the Fermi level. Such effects are obvious for the small zigzag and chiral single-walled carbon nanotubes. The energy gaps decrease as the diameters and the chiral angles of the tubes increase, while the top of the valence band and the bottom of the conduction band of armchair tubes cross at the Fermi level. The numeral results agree well with the experimental results.
杨杰董全力江兆潭张杰
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