Spatial distributions of traffic-related pollutants in street canyons were investigated by field measurements and Computational Fluid Dynamics （CFD）. Two typical street canyons were selected for field monitoring, and a three-dimensional numerical model was built based on Reynolds-averaged Navier-Stokes equations equipped with the standard κ-ε turbulence models for CFD simulations. The study shows that the pollutant concentrations of vehicle emission correlate well with the traffic volume variation, wind direction and wind speed. The wind direction and speed at the roof level determine overwhellmingly the flow field and the distributions of pollutant concentrations in the street canyon. When the wind speed is equal to zero, the pollutant concentrations on the breath height of the both sides of the street canyon are almost the same. When the wind direction is perpendicular to the street, one main vortex is formed with a shape depending on the building structure on both sides of the street, the pollutant is accumulated on the leeward side, and the pollutant concentrations at the breath height on the leeward side are 2 to 3 times as those at the breath height on the windward side. If the wind direction makes some angles with the street canyon, the pollutant concentration will be higher on the leeward side because one main vortex will also be formed in the vertical section of the canyon by the perpendicular component of the wind. But pollutant concentrations decrease in the canyon because pollutants are dispersed along the axis of the street. Pollutants at different heights of the vertical section decrease with height, i.e. there are concentration gradients in the vertical section, and the pollutant concentrations on the leeward side of the upstream building are much higher than those on the windward side of the downstream building.
