For the state control problem in finite-dimensional quantum systems with any initial state and a goal eigenstate, this paper studies the design method of control laws via the Lyapunov technology and in the vector frame, which ensures the convergence of any initial state toward the goal state. The stability of the closed-loop system in the goal eigenstate is analyzed and proven via the invariance principle. The simulation experiment on a spin-1/2 system shows the effectiveness of the designed control laws.