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苏宏庭

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TiO2奈米粒子应用于染料敏化太阳能电池光电极之研究
本文是研究以三种奈米级氧化钛材料;放电式奈米流体制程(EDNP)产出二氧化钛(TiO2)奈米粒子、商用P25(TiO2)粒子以及利用水热式化学反应改质P25而成的氧化钛(TiO)奈米管,分别应用于染料敏化太阳能电池的光电...
苏宏庭
关键词:电泳沉积光电极锐钛矿光电转换效率
TiO2 Nanoparticles Produced by Electric-Discharge-Nanofluid-Process as Photoelectrode of DSSC
2010年
Self-made TiO2 nanoparticles were used as photoelectrode material of dye sensitized solar cell. The TiO2 thin film coats through spreading nanoparticles evenly onto the ITO glass via self-made spin-heat platform, and then TiO2 thin film is soaked in the dye N-719 more than 12 h to prepare the photoelectrode device. The TiO2 nanoparticles produced by electric-discharge-nanofluid-process have premium anatase crystal property, and its diameter can be controlled within a range of 20-50 nm. The surface energy zeta potential of nanofluid is from -22 mV to -28.8 mV, it is a stable particle suspension in the deionized water. A trace of surfactant Triton X-100 put upon the surface of ITO glass can produce a uniform and dense TiO2 thin film and heating up the spin platform to 200 oC is able to eliminate mixed surfac-tant. Self-made TiO2 film presents excellent dye absorption performance and even doesn't need heat treatment procedure to enhance essential property. Results of energy analysis show the thicker film structure will increase the short-circuit current density that causes higher conversion efficiency. But, as the film structure is large and thick, both the open-circuit voltage and fill factor will decline gradually to lead bad efficiency of dye-sensitized solar cell.
陈希立苏宏庭张合卓清松冯啸儒
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